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Liouville equation

The time evolution of the density function is needed to discuss the time evolution of the correlations and information correlation functions. The key characteristic of the density function is that it integrates to one, which implies the probability conservation equation in general, then more specifically a flow equation when a velocity field is definable (deterministic continuous dynamics), and the Liouville equation when in addition the dynamics is Hamiltonian. In this section we discuss the development of the Liouville equation for the full density function, and the corresponding equations for the reduced density functions.

In general, let tex2html_wrap_inline14131 be the density function describing the probabilities of seeing state x at time t. Since the probability at any time of seeing some state is one, we have tex2html_wrap_inline14137. Microscopically, consider a volume element V and the probability in this element at time ttex2html_wrap_inline14143. In general the time evolution of a set of many variables is not going to be deterministic (in the sense that the future state of the system is not specified by the present state of the system alone), such as in any relaxation process driven by radiative cooling or by other interactions of the system with a high complexity and uncertainty outside world. However, if the systems described by the density function evolve deterministically and continuously then it is possible to define a velocity field on the space of states tex2html_wrap_inline13239. The velocity field is simply given by the rate of change of system points. Then, the change in the probability within V with respect to time is due to the flow through the surface S of the volume element, so we write
equation1542
With the use of Gauss' theorem, the surface integral may be rewritten and we find
equation1555
Taking the small volume limit in equation 5.2, the probability conservation equation, gives us the equation of continuity
equation1919
So far this equation holds whenever a velocity field tex2html_wrap_inline14177 is definable. In the case of Hamiltonian evolution, it turns out that the probability density behaves like an incompressible fluid. We show this by considering Hamilton's equations tex2html_wrap_inline14179 and tex2html_wrap_inline14181 for each component of the coordinate and conjugate momentum. Operate with the divergence so that
equation1577
Then, noting that tex2html_wrap_inline14191 and making the substitutions from Hamilton's equations we find for Hamiltonian evolution that tex2html_wrap_inline14193 and
equation1587
where tex2html_wrap_inline14199, the sum over components being implicit. Finally, noting that we may take the volume small, and noting that tex2html_wrap_inline14201 we find for Hamiltonian evolution
equation1600
which is known as Liouville's equation. The total time derivative of the density being zero indicates that the density at any time evolving system point remains constant, and that in turn the volume integral of any point function of the density, such as the entropy or information correlation functions, remains constant.

In summary we have gone from a very general notion of probability conservation, through the addition of the information that the system evolves deterministically, to the additional constraint that the system evolves according to a Hamiltonian.


nextuppreviouscontents
Next:Reduced density functions and Up:Classical equations of information Previous:Classical equations of information
David Wolf

Tue Mar 25 08:11:49 CST 1997